Bis{2-methoxy-6-[3-(methylamino)propyliminomethyl]phenolato}nickel(II) bis(perchlorate)
نویسنده
چکیده
The asymmetric unit of the title compound, [Ni(C(12)H(18)N(2)O(2))(2)](ClO(4))(2), consists of one-half of a centrosymmetric mononuclear Schiff base nickel(II) complex cation and one perchlorate anion. The Ni(II) ion, lying on the inversion center, is coordinated by two N atoms and two O atoms from two Schiff base ligands, forming a square-planar geometry. The crystal packing is stabilized by N-H⋯O hydrogen bonds.
منابع مشابه
Di-μ-thiocyanato-κ4 N:N-bis({5-methoxy-2-[3-(methylamino)propyliminomethyl]phenolato-κ3 O 1,N,N′}copper(II))
The title thio-cyanate-bridged dinuclear copper(II) complex, [Cu(2)(C(12)H(17)N(2)O(2))(2)(NCS)(2)], possesses crystallographic inversion symmetry. Each Cu(II) atom is five-coordinated by one imine N, one amine N and one phenolate O atom of the Schiff base ligand, and by two N atoms from two bridging thio-cyanate ligands, forming a square-pyramidal geometry. Beside the two thio-cyanate bridges,...
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